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Sunday, 11 May 2025

Rust protection experiment after 7 days

I've been thinking about how to stop the tools and machinery in my shed from rusting. Every now and then I come across a tip but have no idea if it's a good solution or not.



To protect my lathe, I simply make sure it's well oiled and I cover it in an oil soaked sheet.

To find out for myself what rust protection treatments work and to satisfy myself that I am protecting my lathe, I decided to do a simplistic experiment.

I cleaned up and cut up a bar of steel. It was initially covered in surface rust, so I knew it was the right type of steel.




I've coated them in different things that I had to hand. They are a bit of a random selection and not all are suitable for the same applications.

The mineral oil based products probably don't need any explanation. That's ISO 68 oil (2), white marine grease (7) and multipurpose lithium based grease (8). Those sorts of things are common in most workshops and, I assume, most people are familiar with coating things in oil or grease to keep rust at bay. Their disadvantage is that they wear off easily.



The caustic soda (9) probably needs the most explanation. This is sodium hydroxide, chemical symbol NaOH. Usually used as a drain cleaner. According to what I have read, rust needs a moist or acidic atmosphere. NaOH is alkaline. The residue on the surface of the metal forms an alkaline solution when it gets moist. This should, to some degree, protect the steel against rust but will need a top up wash whenever the surface is disturbed.
It's big advantage is that the film on the surface is not sticky. This makes it useful for things like woodworking machines where oil would hold sawdust and contaminate the finished product.




I use silicone oil (6) over finished painted surfaces to keep them clean. It's disadvantage is that once used, it can be very difficult to ever get anything to stick to the surface again! As an anti-rust treatment that longevity on the surface should work to our advantage. So I've read.
It's non-toxic and environmentally harmless, so it sounds perfect.
It's one of the reasons I decided to give this experiment a go. When you see the results, you can see why I was glad I tried this for myself.


Water displacement formula, 40th attempt, or so the rumours go. WD-40 (4) is probably well known to most of us. I've used it for years, for lots of things, mainly as a cleaner, for getting stuck things moving again and to try to stop things rusting. It wears off or perhaps evaporates over time, so needs regular re-treatment.



ACF-50 (5) is an anti-corrosion product with the addition that it is also a lubricant. I originally bought it because there was a claim that it stops car locks freezing stuck in cold weather. I'm not entirely convinced about that claim, at least it's not reliable for that purpose on my cars. However, as a surface treatment and lubricant, it has it's uses and tends to stay put for longer than alternative similar products that I had used for years.



Owatrol oil (3) is completely different to the other products. It's easiest thought of as a varnish for steel. It's of no use for machine surfaces but might be OK on extension handles and shanks that don't get any wear. It's sticky when applied and usually takes several days before it can be handled. Commonly used on steel ornamental objects that are going to live outside. I had some, and wanted to see how it stood up.



I have put all my test strips outside but, unusually for the UK, at the moment the weather is not conducive to rust. It's been very dry so I've had to spray them with water, from time to time, to help things along.

Results after 7 days

1. Control - no treatment - clearly starting to rust.

2. Slideway oil (ISO 68) - no sign of rust.
This validates my method of keeping my lathe rust free.

3. Owatrol oil - no sign of rust.
I think this confirms that it does what it is designed to do.




4. WD-40 - no sign of rust.
It leaves a yellowish colour film on the surface. This is still likely to be my first choice to quicky give some protection to tools.

5. ACF-50 - no sign of rust.
This is the cleanest looking sample. It was easy to apply and based on these results it is likely to be my go to product for rust protection of more valuable machine parts.

6. Silicone oil - dots of rust forming.
This is not what I had expected from what I had seen elsewhere online. It does slow down the formation of rust but it's not perfect and its properties offer nothing significant above the mineral oil based methods. It's disappointing, but silicone oil, as a rust treatment, is unlikely to be useful for me.




7. White marine grease - no sign of rust.
It's a bit messy. As expected, I've confirmed that it works to inhibit rust. Where I need to apply that type of grease it's also going to protect against rust, but I'm not going out of my way to use it elsewhere.

8. Multipurpose lithium based grease - no sign of rust.
It inhibits rust and lubricates. Like the white grease, it's useful where it's needed as a lubricant, but there is no real advantage trying to use it elsewhere.

9. Caustic soda - weak solution of drain cleaner wiped over the surface - dots of rust forming.
It clearly reduces the formation of rust and I can see that a non-sticky finish could be useful for a number of applications, but it does not completely prevent rust.


I have two other bits of steel, slightly outside my main experiment.

Nickel Electroplate

The bar I recently electroplated with nickel has started to rust, but only in some places.
It looks like, if I could get a good coating all over the steel, it would be protected. With that knowledge, I now know to clean up the surface better when I electroplate a finished part that I want to also protect from rust.

The other bit (A) is cut from the same bar as the rest of the test strips. It's an untreated piece that I have left inside the workshop, in the dry. That is showing no signs of rust.

Kept inside

I also have some parts that I cold blued some time ago. They have been stored randomly in the old and now the new workshop and none of them have started to rust.

Conclusions

Any mineral oil based coating will protect from rust until it wears off. The tried and tested WD-40 works. |Alongside that, if it is to hand, ACF-50 is quick to apply to parts and has worked well, so far, in my tests.


Temperature (C) and humidity (%)


As a consequence of the dry weather, I have an additional observation that would be useful for the workshop. That is, if the relative humidity can be kept below about 50%, then the steel won't rust.

These one-off results are not to be taken as definitive. I need to do them again, a few more times, to check what is repeatable, before I make my final choices.

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Monday, 5 May 2025

Another garden table

I've been waiting for some local oak to build this table. It arrive yesterday, so today I built the table.


It's green English oak from a tree that came from a field about 4 miles away. It had fallen down and was milled locally to the sizes I requested.
















There's a few finishing touches to complete, but essentially it is done.



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Sunday, 4 May 2025

Quick reference for nickel plating at home

I have been thinking about what I could use to protect parts from rust. Mainly things made on the lathe. I've used cold bluing, which works nicely, but I would like something more robust. Nickel plating came up as a possible solution and looked like a fun project.
There are loads of articles about how to nickel and copper plate parts at home, this is my simplified reminder sheet.


Warnings

"Use Outside - The acid fumes promote rust"
"Well Ventilated - The electrolyte bath creates a fine mist"
"Poison - Do Not Drink"



Make Nickel Electrolyte

Although the ingredients are safe, the resulting nickel electrolyte solution is poisonous!
The electrolyte only needs to be made once and can be kept in a sealed container, almost indefinitely.

Requirements:
  • Container - glass jar with a lid or sealable plastic tub.
  • Power supply - 6V to 12V low current. Less than 1A is sufficient.
  • Anode - pure nickel
  • Cathode - pure nickel
  • White Vinegar (distilled)
  • Table salt (sodium chloride)



Process:
  • Pour white vinegar into the container.
  • Add about 1 small teaspoon of salt for each litre. Not too much. The salt increases the electrical current (reduces the resistance) through the liquid.
  • Hook both bits of nickel over the lip of the jar, or suspend from copper wires, so some of the nickel is in the liquid. The two nickel nodes must not touch and should be as far apart as reasonably possible.
  • Connect the positive to one bit of nickel and the negative to the other.
  • Turn on the power. I used 9V which induced a 0.6A current.
  • Bubbles should start to form on one of the bits of nickel.
  • Leave for about two hours or until the liquid has turned an even shade of light green.

That liquid is the nickel electrolyte.
It's poisonous if consumed, so wash your hands and keep away from animals and children.







The solution starts to go green fairly soon after starting.





After a couple of hours the liquid is clearly green.



Nickel Plate Something

Requirements:
  • The nickel electrolyte solution in a suitably sized container.
  • Power supply - 1V to 3V low current. Less than 1A is sufficient. The lower the voltage the better the surface finish. The voltage does depend on the volume of liquid, but this is assuming it is for a small home setup.
  • Pure nickel anode.
  • The part to be plated is the cathode.

Clean the part:
The part to be plated must be completely free of grease and oxidation.
  • Clean with soap and water, brake cleaning or isopropyl alcohol.
  • For steel the part will need to have all of the rust and mill scale abraded off.
  • Ideally any oxidation should be acid etched away. Using something like a hydrochloric acid solution or, I prefer, a slightly safer phosphoric acid based cleaner, such as T-wash (mordant solution). Any acid in the atmosphere will promote rust, so this step is best done outside.
  • Rinse off in clean water.




Process:
  • Suspend the nickel anode in the electrolyte solution.
  • Suspend the part to be plated in the electrolyte solution on copper wire.
  • The part and the anode must not touch and should be as far apart as reasonably possible.
  • Connect the positive lead to the nickel anode.
  • Connect the negative lead to the part.
  • Turn on the power. I found 1.5V too low. I needed 3V to get an even coat in about 2 hours.
  • Bubbles should start to form on the part.
  • Monitor the results from time to time. Checking and turning the part. My sample took about 2 hours to get an even coverage.





At the end of that, the part should be evenly nickel plated.


Upper nickel plated, lower untreated steel


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Additional Notes:

The power supply can be any source. A battery will work just as well for the plating, but a mains power supply is more practical for creating the electrolyte.

Sodium Bicarbonate neutralises hydrochloric and other acids.

In place of T-wash, I noticed that a ceramic and concrete cleaner contained phosphoric acid in concentrations suitable to etch the surface of steel.

According to some articles, the bubbles that form are hydrogen gas from the cathode part and oxygen from the nickel anode.

Reference:




Saturday, 3 May 2025

Using a different paint technique

This one had an airbrushed base layer, as before, but I used layering and glazing to get the highlights and shadows.




Side by side, I'm not sure which style I prefer. At the moment, I find using a wash and then dry brushing a more satisfying technique to apply.


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